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March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure (en Inglés)
Michael B. Smith (Autor)
·
Wiley
· Tapa Dura
March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure (en Inglés) - Michael B. Smith
Ciencia y matemáticas
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Reseña del libro "March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure (en Inglés)"
Preface Biographical Statement Part 1 Chapter 1: Localized Chemical Bonding 1. A Covalent Bonding 1. B Multiple Valence 1. C Hybridization 1. D Multiple Bonds 1. E Photoelectron Spectroscopy 1. F Electronic Structures Of Molecules 1. G Electronegativity 1. H Dipole Moment 1. I Inductive And Field Effects 1. J Bond Distances 1. K Bond Angles 1. L Bond Energies Chapter Two: Delocalized Chemical Bonding 2. A Molecular Orbitals 2. B Bond Energies And Distances In Compounds Containing Delocalized Bonds 2. C Molecules That Have Delocalized Bonds 2. D Cross Conjugation 2. E The Rules Of Resonance 2. F The Resonance Effect 2. G Steric Inhibition Of Resonance And The Influences Of Strain 2. H P - D Bonding. Ylids 2. I Aromaticity 2. J Alternant And Nonalternant Hydrocarbons 2. K Aromatic Systems With Electron Numbers Other Than Six 2. L Other Aromatic Compounds 2. M Hyperconjugation 2. N Tautomerism 3 Bonding Weaker Than Covalent 3. A Hydrogen Bonding 3. B ()Interactions 3. C Addition Compounds 3. D Catenanes And Rotaxanes 3. E Cucurbit[N]Uril - Based Gyroscane 4 Stereochemistry And Conformation 4. A Optical Activity And Chirality 4. B Dependence Of Rotation On Conditions Of Measurement 4. C What Kinds Of Molecules Display Optical Activity? 4. D The Fischer Projection 4. E Absolute Configuration 4. E. I The Cahn - Ingold - Prelog System 4. F The Cause Of Optical Activity 4. G Molecules With More Than One Stereogenic Center 4. H Asymmetric Synthesis 4. I Methods Of Resolution 4. J Optical Purity 4. K Cis - Trans Isomerism 4. L Out - In Isomerism 4. M Enantiotopic And Diastereotopic Atoms, Groups, And Faces 4. N Stereospecific And Stereoselective Syntheses 4. O Conformational Analysis 4. P Molecular Mechanics 4. Q Strain 5 Carbocations, Carbanions, Free Radicals, Carbenes, And Nitrenes 5. A Carbocations 5. B Carbanions 5. C Free Radicals 5. D Carbenes 5. E Nitrenes 6 Mechanisms And Methods Of Determining Them 6. A Types Of Mechanism 6. B Types Of Reaction 6. C Thermodynamic Requirements For Reaction 6. D Kinetic Requirements For Reaction 6. E The Baldwin Rules For Ring Closure 6. F Kinetic And Thermodynamic Control 6. G The Hammond Postulate 6. H Microscopic Reversibility 6. I Marcus Theory 6. J Methods Of Determining Mechanisms 7 Irradiation Processes In Organic Chemistry 7. A Photochemistry 7. B Sonochemistry 7. C Microwave Chemistry 8 Acids And Bases 8. A Bronsted Theory 8. B The Mechanism Of Proton Transfer Reactions 8. C Measurements Of Solvent Acidity 8. D Acid And Base Catalysis 8. E Lewis Acids And Bases 8. F The Effects Of Structure On The Strengths Of Acids And Bases 8. G The Effects Of The Medium On Acid And Base Strength 9 Effects Of Structure And Medium On Reactivity 9. A Resonance And Field Effects 9. B Steric Effects 9. C Quantitative Treatments Of The Effect Of Structure On Reactivity 9. D Effect Of Medium On Reactivity And Rate Part 2 9. E Iupac Nomenclature For Transformations 9. F Iupac System For Symbolic Representation Of Mechanisms 9. G Organic Syntheses References 10 Aliphatic Substitution, Nucleophilic And Organometallic 10. A Mechanisms 10. B Set Mechanisms 10. C The Neighboring - Group Mechanism 10. D The Sni Mechanism 10. E Nucleophilic Substitution At An Allylic Carbon: Allylic Rearrangements 10. F Nucleophilic Substitution At An Aliphatic Trigonal Carbon: The Tetrahedral Mechanism 10. G Reactivity 10. H Reactions 11 Aromatic Substitution, Electrophilic 11. A Mechanisms 11. B Orientation And Reactivity 11. C Quantitative Treatments Of Reactivity In The Substrate 11. D A Quantitative Treatment Of Reactivity Of The Electrophile: The Selectivity Relationship 11. E The Effect Of The Leaving Group 11. F Reactions 12 Aliphatic, Alkenyl, And Alkynyl Substitution, Electrophilic And Organometallic 12. A Mechanisms 12. B Reactivity 12. C Reactions 13 Aromatic Substitution, Nucleophilic And Organometallic 13. A Mechanisms 13. B Reactivity 13. C Reactions 14 Substitution Reactions, Radical 14. A Mechanisms 14. B Reactivity 14. C Reactions 15 Addition To Carbon - Carbon Multiple Bonds 15. A Mechanisms 15. B Orientation And Reactivity 15. C Reactions C16 Addition To Carbon - Hetero Multiple Bonds 16. A Mechanism And Reactivity 16. A. I Nucleophilic Substitution At An Aliphatic Trigonal Carbon. The Tetrahedral Mechanism 16. B Reactions Chapter 17 Eliminations 17. A Mechanisms And Orientation 17. B Regiochemistry Of The Double Bond 17. C Stereochemistry Of The Double Bond 17. D Reactivity 17. E Mechanisms And Orientation In Pyrolytic Eliminations 17. F Reactions Chapter 18 Rearrangements 18. A Mechanisms 18. B Longer Nucleophilic Rearrangements 18. C Free - Radical Rearrangements 18. D Carbene Rearrangements 18. E Electrophilic Rearrangements 18. F Reactions Chapter 19 Oxidations And Reductions 19. A Mechanisms 19. B Reactions Appendix A: The Literature Of Organic Chemistry Appendix B Classification Of Reactions By Type Of Compounds Synthesized Author Index Index
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